Isotope fractionation of neon during stepheating extraction?: a comment on ‘Re‐interpretation of the existence of a primitive plume under Australia based on neon isotope fractionation during step heating’ by Gautheron and Moreira (2003)     

Takuya Matsumoto  Masahiko Honda  Ian McDougall  Igor Yatsevich  Suzanne Y. O'Reilly 《地学学报》2004,16(1):23-26

Using a Rayleigh distillation fractionation model, we calculate that the maximum isotope fractionation potentially achievable is less than 5% during the early stages of gas release from a sample. Our calculation corrects the erroneous conclusions of Gautheron and Moreira (2003), who re‐interpreted the plume‐like neon isotopic compositions found in metasomatic apatite from a south‐eastern Australian xenolith (Matsumoto et al., 1997) to be the result of Rayleigh‐type isotope fractionation of originally MORB‐type neon during stepheating gas extraction. We stress that the modelling of neon isotopic fractionation by Gautheron and Moreira (2003) is incorrect, and that the finding of a plume‐like neon isotopic composition in the apatite by Matsumoto et al. (1997) remains a quite valid and robust conclusion.  相似文献   

Temperature effects on non-bridging oxygen and aluminum coordination number in calcium aluminosilicate glasses and melts     

Jonathan F. Stebbins  Emily V. Dubinsky  Koji Kanehashi  Kimberly E. Kelsey 《Geochimica et cosmochimica acta》2008,72(3):910-925

Configurational changes with temperature are important for the thermodynamic and transport properties of most aluminosilicate melts, but in general are not well understood. Here, we present high-resolution ²⁷Al and ¹⁷O NMR data on several calcium aluminosilicate glasses prepared with varying quench rates and thus with fictive temperatures that span ranges up to about 200 K. In all compositions the content of five-coordinated aluminum increases with fictive temperature, in agreement with recent high temperature NMR data on melts. In a glass of CaAl₂Si₂O₈ (“anorthite”) composition, the content of non-bridging oxygens also increases with temperature; however this effect was not observed in a sample with a much higher CaO/Al₂O₃ ratio. We present a consistent notation for reactions among structural species in these systems that clarify why in some cases, high-coordinated network cations may appear on the same side of the reaction, while in others they occur on the opposite sides: the key difference is in accounting for all coordination changes for oxygens. Mixing of non-bridging oxygens and of high-coordinated aluminum make significant contributions to the overall configurational entropy and heat capacity of the melts, as does the mixing of various bridging oxygens and of tetrahedral network cations. Other, less well known, types of increase in disorder with temperature may be important as well.  相似文献   

Convergence,divergence and vertical velocity at a tidal front in Hiuchi-Nada,Japan   总被引：2，自引：0，他引：2  

Tetsuo Yanagi  Koji Ishikawa  Koh-ichi Inoue  Satoshi Susami 《Journal of Oceanography》1995,51(2):225-238

The detailed flow structure around a tical front in Hiuchi-Nada, Japan was observed with the use of ADCP (Acoustic Doppler Current Profiler). The surface convergence region is observed at the transition zone between vertically well mixed area and the stratified area. The surface divergence regions exist next to the surface convergence region. The strong downward current is estimated in the middle layer just below the surface convergence region. The maximum surface convergence and the maximum downward velocity in the middle layer are 1.0×10^–4 s^–1 and 0.12 cm s^–1, respectively.  相似文献   

Gravity Anomaly and Tectonics in the Northern Part of the North Fiji Basin - Preliminary Result of the 1994 NOFI Cruise under the NEW STARMER Programme     

Matsumoto  Takeshi  Goslin  Jean  Lagabrielle  Yves  Ruellan  Etienne  Tanahashi  Manabu 《Marine Geophysical Researches》1997,19(1):37-53

A surface ship gravity survey was carried out in the northern part of the North Fiji Basin during the NOFI cruise by the R/V l'Atalante in August-September, 1994. The two ridges inside the study area, the South Pandora Ridge and the Tripartite Ridge, present different structures and states of isostatic equilibrium in terms of gravity anomaly and its tectonic implications. The former is supported by a restoring force of an imaginary elastic plate in the crust and the latter by the Airy type isostasy. These characteristics can be derived from the difference in magmatic activity, as influenced by the difference in lithospheric structure. The latter is characterised by greater active magmatism and hydrothermalism underneath the ridge than the former. Such a difference in the magmatic activity and the horizontal scale of the shallow subsurface structure is derived from the difference in the stiffness or viscosity of the lithosphere beneath the two ridges.  相似文献   

Northward transport of pacific summer water along the Northwind Ridge in the Western Arctic Ocean     

Hiroshi Sumata  Koji Shimada 《Journal of Oceanography》2007,63(3):363-378

The recent sea-ice reduction in the Arctic Ocean is not spatially uniform, but is disproportionally large around the Northwind Ridge and Chukchi Plateau compared to elsewhere in the Canada Basin. In the Northwind Ridge region, Pacific Summer Water (PSW) delivered from the Bering Sea occupies the subsurface layer. The spatial distribution of warm PSW shows a quite similar pattern to the recent ice retreat, suggesting the influence of PSW on the sea-ice reduction. To understand the regionality of the recent ice retreat, we examine the dynamics and timing of the delivery of the PSW into this region. Here, we adopt a two-layer linearized potential vorticity equation to investigate the behavior of Rossby waves in the presence of a topographic discontinuity in the high latitude ocean. The analytical results show a quite different structure from those of mid-latitude basins due to the small value of β. Incident barotropic waves excited by the sea-ice motion with large annual variation can be scattered into both barotropic and baroclinic modes at the discontinuity. Since the scattered baroclinic Rossby wave with annual frequency cannot propagate freely, a strong baroclinic current near the topographic discontinuity is established. The seasonal variation of current near the topographic discontinuity would cause a kind of selective switching system for shelf water transport into the basin. In our simple analytical model, the enhanced northward transport of summer water and reduced northward transport of winter water are well demonstrated. The present study indicates that these basic dynamics imply that a strengthening of the surface forcing during winter in the Canada Basin could cause sea-ice reduction in the Western Arctic through the changes of underlying Pacific Summer Water.  相似文献   

Active spreading and hydrothermalism in North Fiji Basin (SW Pacific). Results of Japanese French Cruise Kaiyo 87     

Jean-Marie Auzende  Eiichi Honza  Xavier Boespflug  Satendra Deo  Jean-Philippe Eissen  Jun Hashimoto  Philippe Huchon  Junichiro Ishibashi  Yo Iwabuchi  Philip Jarvis  Masato Joshima  Kiyoyuki Kisimoto  Yasuto Kuwahara  Yves Lafoy  Tsuyoshi Matsumoto  Jean-Pierre Maze  Kiyohiko Mitsuzawa  Hiroyasu Monma  Takeshi Naganuma  Yukihiro Nojiri  Suguru Ohta  Kiyoshi Otsuka  Yoshihisa Okuda  Hélène Ondreas  Akira Otsuki  Etienne Ruellan  Myriam Sibuet  Manabu Tanahashi  Takeo Tanaka  Tetsuro Urabe 《Marine Geophysical Researches》1990,12(4):269-283

The aim of the Japanese-French Kaiyo 87 cruise was the study of the spreading axis in the North Fiji Basin (SW Pacific). A Seabeam and geophysical survey allowed us to define the detailed structure of the active NS spreading axis between 16° and 22° S and its relationships with the left lateral motion of the North Fiji Fracture Zone. Between 21° S and 18°10′ S, the spreading axis trends NS. From 18°10 S to 16°40 S the orientation of the spreading axis changes from NS to 015°. North of 16°40′ S the spreading axis trends 160°. These two 015° and 160° branches converge with the left lateral North Fiji fracture zone around 16°40′ S to define an RRFZ triple junction. Water sampling, dredging and photo TV deep towing give new information concerning the hydrothermal activity along the spreading axis. The discovery of hydrothermal deposits associated with living communities confirms this activity.  相似文献   

Responses of phytoplankton and heterotrophic bacteria in the northwest subarctic Pacific to in situ iron fertilization as estimated by HPLC pigment analysis and flow cytometry   总被引：3，自引：0，他引：3  

Koji Suzuki  Akira Hinuma  Hiroaki Saito  Hiroshi Kiyosawa  Hongbin Liu  Toshiro Saino  Atsushi Tsuda 《Progress in Oceanography》2005,64(2-4):167

To verify the hypothesis that the growth of phytoplankton in the Western Subarctic Gyre (WSG), which is located in the northwest subarctic Pacific, is suppressed by low iron (Fe) availability, an in situ Fe fertilization experiment was carried out in the summer of 2001. Changes over time in the abundance and community structure of phytoplankton were examined inside and outside an Fe patch using phytoplankton pigment markers analyzed by high-performance liquid chromatography (HPLC) and flow cytometry (FCM). In addition, the abundance of heterotrophic bacteria was also investigated by FCM. The chlorophyll a concentration was initially ca. 0.9 μg l⁻¹ in the surface mixed layer where diatoms and chlorophyll b-containing green algae (prasinophytes and chlorophytes) were predominant in the chlorophyll biomass. After the iron enrichment, the chlorophyll a concentration increased up to 9.1 μg l⁻¹ in the upper 10 m inside the Fe patch on Day 13. At the same time, the concentration of fucoxanthin (a diatom marker) increased 45-fold in the Fe patch, and diatoms accounted for a maximum 69% of the chlorophyll biomass. This result was consistent with a microscopic observation showing that the diatom Chaetoceros debilis had bloomed inside the Fe patch. However, chlorophyllide a concentrations also increased in the Fe patch with time, and reached a maximum of 2.2 μg l⁻¹ at 5 m depth on Day 13, suggesting that a marked abundance of senescent algal cells existed at the end of the experiment. The concentration of peridinin (a dinoflagellate marker) also reached a maximum 24-fold, and dinoflagellates had contributed significantly (>15%) to the chlorophyll biomass inside the Fe patch by the end of the experiment. Concentrations of 19′-hexanoyloxyfucoxanthin (a prymnesiophyte marker), 19′-butanoyloxyfucoxanthin (a pelagophyte marker), and alloxanthin (a cryptophyte marker) were only incremented a few-fold increment inside the Fe patch. On the contrary, chlorophyll b concentration reduced to almost half of the initial level in the upper 10 m water column inside the Fe patch at the end of the experiment. A decrease with time in the abundance of eukaryotic ultraphytoplankton (<ca. 5 μm in size), in which chlorophyll b-containing green algae were possibly included was also observed by FCM. Overall, our results indicate that Fe supply can dramatically alter the abundance and community structure of phytoplankton in the WSG. On the other hand, cell density of heterotrophic bacteria inside the Fe patch was maximum at only ca. 1.5-fold higher than that outside the Fe patch. This indicates that heterotrophic bacteria abundance was little respondent to the Fe enrichment.  相似文献   

Community Structure and Dynamics of Phytoplankton in the Western Subarctic Pacific Ocean: A Synthesis   总被引：1，自引：1，他引：1  

Hongbin Liu  Koji Suzuki  Hiroaki Saito 《Journal of Oceanography》2004,60(1):119-137

The phytoplankton community in the western subarctic Pacific (WSP) is composed mostly of pico- and nanophytoplankton. Chlorophyll a (Chl a) in the <2 μm size fraction accounted for more than half of the total Chl a in all seasons, with higher contributions of up to 75% of the total Chl a in summer and fall. The exception is the western boundary along the Kamchatka Peninsula and Kuril Islands and the Oyashio region where diatoms make up the majority of total Chl a during the spring bloom. Among the picophytoplankton, picoeukaryotes and Synechococcus are approximately equally abundant, but the former is more important in term of carbon biomass. Despite the lack of a clear seasonal variation in Chl a concentration, primary productivity showed a large seasonal variation, and was lowest in winter and highest in spring. Seasonal succession in the phytoplankton community is also evident with the abundance of diatoms peaking in May, followed by picoeukaryotes and Synechococcus in summer. The growth of phytoplankton (especially >10 μm cell size) in the western subarctic Pacific is often limited by iron bioavailability, and microzooplankton grazing keeps the standing stock of pico- and nano-phytoplankton low. Compared to the other HNLC regions (the eastern equatorial Pacific, the Southern Ocean, and the eastern subarctic Pacific), iron limitation in the Western Subarctic Gyre (WSG) may be less severe probably due to higher iron concentrations. The Oyashio region has similar physical condition, macronutrient supply and phytoplankton species compositions to the WSG, but much higher phytoplankton biomass and primary productivity. The difference between the Oyashio region and the WSG is also believed to be the results of difference in iron bioavailability in both regions. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Model simulations of carbon sequestration in the northwest Pacific by patch fertilization     

Katsumi Matsumoto 《Journal of Oceanography》2006,62(6):887-902

Iron fertilization of nutrient-rich surface waters of the ocean is one possible way to help slow the rising levels of atmospheric CO₂ by sequestering it in the oceans via biological carbon export. Here, I use an ocean general circulation model to simulate a patch of nutrient depletion in the subpolar northwest Pacific under various scenarios. Model results confirm that surface fertilization is an inefficient way to sequester carbon from the atmosphere (Gnanadesikan et al., 2003), since only about 20% of the exported carbon comes initially from the atmosphere. Fertilization reduces future production and thus CO₂ uptake by utilizing nutrients that would otherwise be available later. Effectively, this can be considered as leakage when compared to a control run. This “effective” leakage and the actual leakage of sequestered CO₂ cause a significant, rapid decrease in carbon retention (only 30–45% retained after 10 years and less than 20% after 50 years). This contrasts markedly with the almost 100% retention efficiency for the same duration using the same model, when carbon is disposed directly into the northwest Pacific (Matsumoto and Mignone, 2005). As a consequence, the economic effectiveness of patch fertilization is poor in two limiting cases of the future price path of carbon. Sequestered carbon in patch fertilization is lost to the atmosphere at increasingly remote places as time passes, which would make monitoring exceedingly difficult. If all organic carbon from one-time fertilization reached the ocean bottom and remineralized there, acidification would be about −0.05 pH unit with O₂ depletion about −20 μmol kg⁻¹. These anomalies are probably too small to seriously threaten deep sea biota, but they are underestimated in the model because of its large grid size. The results from this study offer little to advocate purposeful surface fertilization as a serious means to address the anthropogenic carbon problem.  相似文献   

Comparison of bromodeoxyuridine immunoassay with tritiated thymidine radioassay for measuring bacterial productivity in oceanic waters     

Koji Hamasaki 《Journal of Oceanography》2006,62(6):793-799

Recently, bromodeoxyuridine (BrdU) has been successfully applied to the measurement of bacterial productivity as an alternative to tritiated thymidine (³H-TdR), which is widely used but often restricted by regulations, particularly in field settings. Here, I report improvements to existing BrdU methods to simplify procedures and increase sensitivity. The feasibility of the method was tested measuring bacterial production in low-productive waters. The method provided radioisotope-free measurements of bacterial production rates at shorter (∼1 h) on-board processing time of samples than previously reported procedures. It was applicable to the detection of rates ranging from 0.021 to 2.7 pmol BrdU l⁻¹h⁻¹. BrdU incorporation rates measured by immunoassay showed a statistically significant correlation with ³H-TdR incorporation rates measured by radioassay (r = 0.74, n = 24, p < 0.001). The linear regression obtained (BrdU = 0.80[³H-TdR] − 0.016) showed a similar relationship to previously reported regressions (BrdU = 0.65[³H-TdR] + 0.12, [³H-BrdU] = 0.69[³H-TdR] − 0.81). There were no statistically significant differences among these regression lines. These results suggest that the method described here provides a non-radioisotopic productivity measurement of bacteria in oceanic epipelagic waters, while retaining continuity of the data with other existing ³H-TdR and BrdU methods.  相似文献